The first method is reviewing posts to uncover the ID assigned to the user and their corresponding username.
The admin user is usually assigned the user ID 1. We can confirm this by specifying the user ID for the author parameter in the URL.
http://blog.inlanefreight.com/?author=1
We can find for non-existing user as such:
JSON Endpoint
The second method requires interaction with the JSON endpoint, which allows us to obtain a list of users. This was changed in WordPress core after version 4.7.1, and later versions only show whether a user is configured or not. Before this release, all users who had published a post were shown by default.